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Zirconolite-rich titanate ceramics for high-level actinide wastes

Conference ·
OSTI ID:47874
; ; ;  [1]
  1. Advanced Materials Program, Ansto (Australia)
New diffraction and microstructural data on the incorporation of rare earths, Np and Pu in nominally single-phase zirconolite (CaZrTi{sub 2}O{sub 7}) are presented. Such data are vital for the crystal-chemical design of zirconolite-rich titanate ceramics of the Synroc family, for the immobilization of up to 30 wt% of actinide wastes from advanced reprocessing/partitioning schemes. Some trial zirconolite-rich ceramics were made with U and Nd simulating tetravalent and trivalent actinides respectively. Some preliminary results to examine chemical flexibility with regards to variations in waste/precursor are given, for different actinide waste compositions.
OSTI ID:
47874
Report Number(s):
CONF-931108--Vol.333
Country of Publication:
United States
Language:
English