Characterization of zeolite L nanoclusters
- California Institute of Technology, Pasadena, CA (United States)
- Univ. of Massachusetts, Amherst, MA (United States)
- Univ. of Tokyo (Japan); and others
Zeolite L (structure code LTL) crystals are synthesized starting from homogeneous potassium aluminosilicate solutions. Particle size and shape of the formed zeolite L are examined by high-resolution transmission electron microscopy, field emission-scanning electron microscopy, X-ray diffraction, and dynamic light scattering. The synthesis conditions reported lead to nanoclusters of aligned zeolite crystalline domains of dimensions {approximately}40 nm in the channel direction and {approximately}15 nm in the direction perpendicular to the zeolite channels. The nanoclusters have sizes of {approximately}60 nm. Electron microscopy of the nanoclusters reveals the presence of inhomogeneities (intercrystalline porosity) on length scales ranging from 2 to 60 nm. The N{sub 2} and cyclohexane adsorption capacities and the thermal stability of the crystals synthesized are correlated with their microstructure. The preparation of colloidal suspensions of the zeolite L nanoclusters in water is described along with their use in seeded growth and film formation. 16 refs., 12 figs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 478315
- Journal Information:
- Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 9 Vol. 7; ISSN CMATEX; ISSN 0897-4756
- Country of Publication:
- United States
- Language:
- English
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