GAS-CHROMATOGRAPHIC SEPARATION OF ORTHO- AND PARAHYDROGEN ON MOLECULAR SIEVES: ANALYSIS, PREPARATION, AND MEASUREMENT OF CATALYTIC CONVERSION AND OF ADSORPTION

Journal Article · Tue May 01 04:00:00 EDT 1962 · J. Catalysis

DOI:https://doi.org/10.1016/0021-9517(62)90015-5· OSTI ID:4778191

Bachmann, L; Bechtold, E; Cremer, E

Ortho- and parahydrogen was separated on molecular speeves. An apparatus for the preparation of pure orthohydrogen and parahydrogen and for the detcrmination of the conversion velocity in the presence of a catalyst is described. If the stationary phase acts as a catalyst during the separation an approximate determination of the conversion velocity can be made from the chromatogram. As there is a simple relationship between the retention volume and the first differential coefficient of the adsorption isotherm, the latter may be obtained from the peak corresponding to one of the components. The adsorption isotherms on molecular sieves Linde 13X and 5A are given. The adsorption enthalpies and the difference of the free enthalpies were also calculated. (auth)

• Research Organization: Universitat, Innsbruck, Austria
• NSA Number: NSA-16-031535
• OSTI ID: 4778191
• Journal Information: J. Catalysis, Journal Name: J. Catalysis Vol. Vol: 1
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ADSORPTION
ADSORPTION ISOTHERMS
CATALYSIS
CHEMISTRY
CHROMATOGRAPHY
HYDROGEN
HYDROGEN-ORTHO
HYDROGEN-PARA
ISOMERS
PREPARATION
QUANTITATIVE ANALYSIS
SEPARATION PROCESSES
THERMODYNAMICS