Synthesis and characterization of rhenium thiolate complexes. Crystal and molecular structures of [NBu{sub 4}][ReO(H{sub 2}O)Br{sub 4}]{center_dot}2H{sub 2}O, [Bu{sub 4}N][ReOBr{sub 4}(OPPh{sub 3})], [ReO(SC{sub 5}H{sub 4}N){sub 3}], [ReO(SC{sub 4}H{sub 3}N{sub 2}){sub 3}][ReO(OH)(SC{sub 5}H{sub 4}N-3,6-(SiMe{sub 2}Bu{sup t}){sub 2}){sub 2}], [Re(N{sub 2}COC{sub 6}H{sub 5})(SC{sub 5}H{sub 4}N)Cl(PPh{sub 3}){sub 2}], and [Re(PPh{sub 3})(SC{sub 4}H{sub 3}N{sub 2}){sub 3}]
- Syracuse Univ., NY (United States); and others
The syntheses and characterization of six monomeric rhenium thiolate complexes and the structural characterization of two useful rhenium starting materials are presented. Pyridine-2-thiol (2), 3,6-bis(dimethyl-tert-butylsilyl)pyridine-2-thiol (3), and pyrimidine-2-thiol (4) were reacted with [Bu{sub 4}N][ReOBr{sub 4}(H{sub 2}O)]{center_dot}2H{sub 2}O (5), [Bu{sub 4}N][ReOBr{sub 4}(OPPh{sub 3})] (6), [ReO{sub 2}(C{sub 5}H{sub 5}N){sub 4}], and [Re(N{sub 2}CO(C{sub 6}H{sub 5}))Cl{sub 2}(PPh{sub 3}){sub 2}] to give [ReO(C{sub 5}H{sub 4}NS){sub 3}] (7), [ReO(C{sub 8}H{sub 12}NSiS){sub 3}] (8), [ReO(OH)(C{sub 11}H{sub 20}NSi{sub 2}S){sub 2}] (9), [Re(N{sub 2}-CO(C{sub 6}H{sub 5}))Cl(PPh{sub 3}){sub 2}(C{sub 5}H{sub 4}NS)] (10), [ReO(C{sub 4}H{sub 3}N{sub 2}S){sub 3}] (11), and [Re(P(C{sub 6}H{sub 5}){sub 3})(C{sub 4}H{sub 3}N{sub 2}S){sub 3}] (12). Crystal structures are reported for the compounds.
- OSTI ID:
- 477556
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 12 Vol. 35; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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