A MOLECULAR-ORBITAL APPROACH TO THE DEVELOPMENT OF VIBRATIONAL POTENTIAL FUNCTIONS: CO FORCE CONSTANT AND STRETCH-STRETCH INTERACTION CONSTANTS FOR METAL HEXACARBONYLS
Journal Article
·
· J. Mol. Spectr.
From a consideration of the molecular-orbitals of carbon monoxide it is shown that the observed CO force constants of the metal carbonyls indicate considerable metalcarbon pi bonding. The seven stretch-stretch interaction constants of the meral hexacarbonyls of octahedral symmetry are reduced to three constants using a molecularorbital development. The results are the same as those derived using a valence-bond approach. (auth)
- Research Organization:
- Los Alamos Scientific Lab., N. Mex.
- NSA Number:
- NSA-17-005108
- OSTI ID:
- 4769460
- Report Number(s):
- TID-14800; LADC-5216
- Journal Information:
- J. Mol. Spectr., Journal Name: J. Mol. Spectr. Vol. Vol: 9
- Country of Publication:
- United States
- Language:
- English
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