MICROWAVE SPECTRUM OF ACETONITRILE-d$sub 3$, CD$sub 3$CN

Journal Article · Thu Nov 01 04:00:00 EST 1962 · J. Mol. Spectry

DOI:https://doi.org/10.1016/0022-2852(62)90244-8· OSTI ID:4765671

Matsumura, C; Hirota, E; Ika, T; Morino, Y

Microwave spectrum for the J = 2 yields 1 transition of the CD/sub 3/ CN molecule was investigated. The molecular structure was determined from the observed spectra of CD/sub 3/CN, C/sub 13/D/sub 3/CN, CD/sub 3/C/sup 13/N, and CD/ sub 3/CN/sup 15/. A number of s pectral lines of the molecule in the excited vibrational states, nu /sub s/, 2 nu /sub s/, 3 nu /sub s/, 4 nu /sub s/, 5 nu / sub s/, nu /sub 7/, nu /sub 6/, nu / sub 4/, and nu /sub 3/, were measured and analyzed. The observed l-type doublings and the splittings in highly excited states were well interpreted by the theory. An anomaly in the Stark pattern of the nu /sub 7/ excited lines was noticed and explained by the accidental near degeneracy of the nu /sub 4/ and nu /sub 7/ vibrations. (auth)

• Research Organization: Tokyo Univ.
• NSA Number: NSA-17-001444
• OSTI ID: 4765671
• Journal Information: J. Mol. Spectry, Journal Name: J. Mol. Spectry Vol. Vol: 9
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ACETIC ACID
CARBON 13
CHEMISTRY
CYANIDES
DEUTERIUM COMPOUNDS
ENERGY LEVELS
EXCITATION
HYPERFINE STRUCTURE
MEASURED VALUES
MICROWAVES
MOLECULES
NITRILES
NITROGEN 15
OSCILLATIONS
PARTICLE MODELS
QUANTITATIVE ANALYSIS
SPECTRA
STARK LEVELS
TRANSIENTS