POLARIZABILITY CHANGE IN LIQUIDS DUE TO MANY-BODY INTERACTIONS
Journal Article
·
· Journal of Chemical Physics (U.S.)
Approximate quantum-mechanical expressions for the change in polarizability due to many-body interactions in spherically symmetric liquids, or dense gases, were derived by a variational form of perturbation theory. The expressions are evaluated using Linder's continuum model for the liquid and Slater-type wavefunctions. It is shown that the change in polarizability is approximately arizability and g is a parameter which depends on the dielectric constant and molar volume of the liquid. The predicted increase in polarizability varied from 0.042% for He to 3.54% for Xe. (auth)
- Research Organization:
- Univ. of Washington, Seattle
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-17-004526
- OSTI ID:
- 4758072
- Journal Information:
- Journal of Chemical Physics (U.S.), Journal Name: Journal of Chemical Physics (U.S.) Vol. Vol: 37; ISSN JCPSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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