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Interdiffusion of Gases in a Low Permeability Graphite at Uniform Pressure

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.1702531· OSTI ID:4747248

An experimental investigation of the interdiffusion behavior of gases in a low-permeability graphite was performed by sweeping the opposite faces of a graphite septum with helium and argon at uniform pressure and measuring the diffusive flux of both gases. The objectives were to ascertain the diffusion mechanism, to verify the applicable equations and associated theories, and to determine the parameters required to use these equations. At all experimental pressures, contributions of both normal and Knudsen diffusion effects were detectable via the pressure dependence of the diffusion fluxes. It was found that a dusty-gas model formed an excellent basis for correlating the results. The dusty-gas model yielded flux equations that predicted the diffusion behavior over a wide range of pressures for particular gas concentrations at the boundaries. Only two experimentally determined parameters (characteristic of the gases and graphite) were required. These were an effective normal-diffusion coefficient obtained through interdiffusion experiments and a Knudsen coefficient obtained through single-gas (permeability) experiments. The procedures used to evaluate these parameters in terms of the experimental data were described.

Research Organization:
Oak Ridge National Lab., Tenn.
Sponsoring Organization:
USDOE
NSA Number:
NSA-16-033498
OSTI ID:
4747248
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 9 Vol. 33; ISSN JAPIAU; ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
Country unknown/Code not available
Language:
English

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