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THEORY OF POSITRON ANNIHILATION IN SODIUM FLUORIDE

Thesis/Dissertation ·
OSTI ID:4741994
A model of an ionic crystal of the Rocksalt structure was made by using free-ion Hartree-Fock electronic wavefunctions for the ions at each of the lattice points. This model is used to compute the wavefunction of a positron in the crystal on the assumption that the positron may be represented by a Bloch- type function not localized at any ion; positron-electron correlations are not considered. The interaction of the positron with the ions is calculated and used to determine the angular correlation of the gamma rays emitted in two-photon annihilation in the crystal. Numerical computations are carried out for polycrystalline NaF, and the resulting angular correlation curves are compared with experimental results. It is found that the model is qualitatively correct, but the theoretical distribution is too wide; it is suggested that the use of free-ion electronic wavefunctions accounts for the error, and that more accurate wavefunctions for ions in a crystal of this type should be computed. It is found that the positron wavefunction is only slightly inclined toward the negative ion, so that one may roughly estimate the proportion of the annihilation which takes place with each type of ion by comparing the volumes of the ions in the crystal. (Dissertation Abst., Vol. 23, No. 7)
Research Organization:
Originating Research Org. not identified
NSA Number:
NSA-17-017301
OSTI ID:
4741994
Country of Publication:
Country unknown/Code not available
Language:
English

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