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THEORY OF ISOTOPE SEPARATION OF HOMO AND HETERONUCLEAR DIATOMIC MOLECULES BY ADSORPTION AT LOW TEMPERATURES

Journal Article · · Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides
OSTI ID:4722227
The ground-state rotational-vibrational energies, E/sub T/, for diatomic molecules adsorbed on plane surfaces were calculated assuming a Morse potential for the surface-molecule interaction. For the moiecular hydrogens it was found that the trend of E/sub T/ as a function of surface barrier, both in units of 8 e (as Fe/sup 59 /sup 2/I/h/sub 2/, is nearly the same for all isotopes. The correlation diagram for the heteronuclear molecules deviates somewhat from that of the homonuclears, the magnitude of the deviation depending on the shift of the center of mass. (auth)
Research Organization:
Ohio State Univ., Columbus
NSA Number:
NSA-17-023807
OSTI ID:
4722227
Journal Information:
Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides, Journal Name: Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides Vol. Vol: 60; ISSN JCPQA
Country of Publication:
Country unknown/Code not available
Language:
English

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