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A STUDY OF FERROELECTRIC MATERIALS. Final Technical Report, September 1, 1961 to August 31, 1962

Technical Report ·
OSTI ID:4712416
The high-temperature structures of NaNbO/sub 3/, radiation effects in ferroelectric materials, and neutron scattering with certain hydrogenous materials and materials showing dielectric anomalies are being studied. For the study of the structure at high temperatures methods were developed for obtaining x-ray single-crystal photographs up to 900 un. Concent 85% C. At 540 un. Concent 85% C a tetragonal perovskite-type structure was confirmed. The super lattice reflections associated with 2- and 4- subcell repeats were found at lower temperatures. A ferroelectric material, on irradiation by neutrons, gamma rays, or x rays, acts as a source of electrical energy. Two types of this radiation sensitivity were observed: one variable and of short time-constant, seen for periods of seconds or minutes after the start of irradiation; the other of long time-constant and stable for months after irradiation. Attempts to correlate radiation sensitivity and thickness of sample were unsuccessful. The neutron spectra of ferroelectric and paraelectric BaTiO/sub 3/, and of a number of hydrogen-bonded structures, were studied and partially interpreted. Evidence was obtained for the existence of a dielectric anomaly at about 20 un. Concent 85% K in TlCl and 50 un. Concent 85% K in TlBr. (auth)
Research Organization:
Cambridge Univ., England. Cavendish Lab.
NSA Number:
NSA-17-023862
OSTI ID:
4712416
Report Number(s):
AD-286036
Country of Publication:
United States
Language:
English

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