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ANNEALING OF NEUTRON RADIATION DAMAGE IN p-TYPE PbTe

Technical Report ·
OSTI ID:4709398
The measurement of conductivity, Seebeck, and Hall coefficient changes in p-type PbTe caused by reactor irradiation was extended in a specimen to a reaction-radiation dose of 4.4 x 10/sup 19/ neutrons/cm/sup 2/ with energy greater than 1 Mev and a thermal-neutron dose of 1.5 x 10/sup 21/ neutrons/ cm/ sup 2/. Sample temperature during irradiation was 60 ction in DDT-C/ 20 nif- C. Permanent changes caused by thermal-neutron transmutations were negligible (< 3 percent), indicating that all the damage is annealable and caused by fast neutron-induced defects. Based on previous irradiation test results and those which follow, a phenomenological model which predicts the behavior of n- and p-type PbTe at possible operating temperatures during reactor irradiation is presented. The carrier-concentration decrease caused by irradiation of the specimen was a factor of 5.3 less than the pretest measurement. This factor accounts for most of the increase in Seebeck coefficient (factor 2.9). Analysis of the annealing effects on electrical conductivity (decreased by a factor 7.6) yields an activation energy for defect migration of sup 14/ recover 0.55 ev. Isothermal annealing experiments indicate the simultaneous recovery of conductivity, Hall, and Seebeck coefficients for temperatures in the range 88 to 162 nif- C. (auth)
Research Organization:
Knolls Atomic Power Lab., Schenectady, N.Y.
DOE Contract Number:
W-31-109-ENG-52
NSA Number:
NSA-17-018857
OSTI ID:
4709398
Report Number(s):
KAPL-2226
Country of Publication:
United States
Language:
English