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Dissociation Energy Computations in Diatomic Molecules. An Example

Journal Article · · Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.1733596· OSTI ID:4704089
It is shown with a specific example that accurate dissociation energies in diatomic molecules can be computed without the need of exact wavefunctions but simply by comparing the self-consistent field energy of the diatomic molecules and the data on atomic correlation energy obtained thus far. The LiF molecule was used as an example.
Research Organization:
International Business Machines Corp., San Jose, Calif.
Sponsoring Organization:
USDOE
NSA Number:
NSA-17-030541
OSTI ID:
4704089
Journal Information:
Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 11 Vol. 38; ISSN JCPSA6; ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
Country unknown/Code not available
Language:
English

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