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THE RADIOLYSIS OF SULFURIC ACID (in Russian)

Journal Article · · Doklady Akademii Nauk SSSR (U.S.S.R.) English translation currently published in a number of subject-oriented journals
OSTI ID:4694537
; ;
Solutions of 0.4 to 18M H/sub 2/SO/sub 4/ were given a dose of 5 x 10/ sup 15/ to 2 x 10/.sup 16/ ev/ml-sec by 65-kev x rays, and Co/sup 60/ gamma ray s in the presence of ferrous sulfate. The concentrations of Fe/sup 3+/ and SO/ sub 2/ were determined spectrophotometrically. The ratio of G(Fe/sup 3+/)/sub O2/ to G(Fe/sup 3+/)/sub N2/ decreased from 1.9 to 1. 8 on increasing the concentration of H/sub 2/SO/sub 4/ from 0.4 to 17.3M. The yield of SO/sub 2/ was 0.61 molecules per 100 ev of absorbed energy, and did not depend on the presence or absence of oxygen. The yield for the decomposition of H/sub 2/SO/sub 4/ was equal to 4.15 molecules per 100 ev in 17.3M H/sub 2/SO/sub 4/. The mechanisms for the reaction for the irradiation of a dilute and a concentrated H/sub 2/SO/ sub 4/ solution are discussed. (TTT)
Research Organization:
Moscow Univ.
NSA Number:
NSA-17-028956
OSTI ID:
4694537
Journal Information:
Doklady Akademii Nauk SSSR (U.S.S.R.) English translation currently published in a number of subject-oriented journals, Journal Name: Doklady Akademii Nauk SSSR (U.S.S.R.) English translation currently published in a number of subject-oriented journals Vol. Vol: 149; ISSN DANKA
Country of Publication:
Country unknown/Code not available
Language:
Russian

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Related Subjects

ABSORPTION
CHEMISTRY
COBALT 60
DECOMPOSITION
ENERGY
GAMMA SOURCES
IRON SULFATES
OXYGEN
PHOTOMETRY
RADIATION CHEMISTRY
RADIOLYSIS
REACTION KINETICS
SOLUTIONS
SPECTROSCOPY
SULFURIC ACID
X RADIATION