THE RADIOLYSIS OF CYCLOHEXANE. IV. THE EFFECT OF SOLUTES ON THE RADIOLYSIS OF LIQUID CYCLOHEXANE

Journal Article · Mon Jul 01 00:00:00 EDT 1963 · Nippon Kagaku Zasshi (Japan) Formerly Nippon Kagaku Kaishi (1921- 47) Merged with Kogyo Kagaku Zasshi to form Nippon Kagaku Kaishi

DOI:https://doi.org/10.1246/nikkashi1948.84.7_561· OSTI ID:4690691

Kikuchi, K; Sato, S; Shida, S

The effect of the addition of vanlous solutes, such as iodine, aromatic and olefinic compounds, and acetylene, on the gamma radiolysis of liquid cyclohexane was investigated by measuring the yield of hydrogen and in some cases those of hydrogenated compounds of the solutes. Addition of solutes decreases G(H/sub 2/) from cyclohexane in the orders; benzene > and ethylene > propylene > acetylene > isobutene. The orders correspond to those of the ability in the radical scavenging. When unsaturated lower hydrocarbons were used as solutes, the hydrogenated compounds of the solutes were detected by gas chromatography, which are considered to be produced by scavenging H atoms. (auth)

• Research Organization: Originating Research Org. not identified
• Sponsoring Organization: USDOE
• NSA Number: NSA-17-040886
• OSTI ID: 4690691
• Journal Information: Nippon Kagaku Zasshi (Japan) Formerly Nippon Kagaku Kaishi (1921- 47) Merged with Kogyo Kagaku Zasshi to form Nippon Kagaku Kaishi, Journal Name: Nippon Kagaku Zasshi (Japan) Formerly Nippon Kagaku Kaishi (1921- 47) Merged with Kogyo Kagaku Zasshi to form Nippon Kagaku Kaishi Vol. Vol: 84; ISSN NPKZA
• Country of Publication: Country unknown/Code not available
• Language: Japanese

Related Subjects

ACETYLENES
ALKENES
ANTHRACENE
AROMATICS
ATOMS
BENZENE
BUTYLENE
CHEMISTRY
CHROMATOGRAPHY
CYCLOALKANES
CYCLOALKENES
DECOMPOSITION
DETECTION
DIPHENYLS
EFFICIENCY
ETHYLENE
FREE RADICALS
G-VALUE
GAMMA RADIATION
GASES
HEXANE
HYDROGEN
HYDROGENATION
IODINE
IRRADIATION
ISOBUTYLENE
ISOMERS
LIQUIDS
MEASURED VALUES
NAPHTHALENE
PHENYL RADICALS
POLYPHENYLS
PRECIPITATION
PROPYLENE
RADIATION CHEMISTRY
RADIOLYSIS
SOLUTIONS