Reaction of furan-based o-quinodimethanes with triplet oxygen. Formation of cyclic peroxides
Journal Article
·
· Journal of Organic Chemistry
- Iowa State Univ., Ames, IA (United States)
Formation of cyclic peroxides 2a,2b, and 2c from the reactions of 2,3-dimethylene-2,3-dihydrofuran (1a) and the 5-methyl (1b) and 5-tert-butyl (1c) derivatives with triplet oxygen is reported. Thermolysis of cyclic peroxide 2c gives dialdehyde 5, hydroxy aldehydes 6 and 7, and diol 8 as products. 1 fig.
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 468727
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 17 Vol. 60; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
Similar Records
I. Kinetic and mechanistic study of the (4+4) dimerization of 2,3-dimethylene-2,3-dihydrofuran. II. Preparation of 2,3-dimethylene-2,3-dihydrogenzo(b)furan by the flash vacuum pyrolysis of 2-methyl-3-benzo(b)furylmethyl benzoate. III. Reaction of 2,3-dimethylene-2,3-dihydrofuran with triplet oxygen
I. Kinetic and mechanistic study of the (4+4) dimerization of 2,3-dimethylene-2,3-dihydrofuran. II. Preparation of 2,3-dimethylene-2,3-dihydrobenzo(B)furan by the flash vacuum pyrolysis of 2-methyl-3-benzo(B)furylmethyl benzoate. III. Reaction of 2,3-dimethylene-2,3-dihydrofuran with triplet oxygen
(4 + 4) dimerization of 2,3-dimethylene-2,3-dihydrofuran: secondary deuterium kinetic isotope effect evidence of a two-step mechanism
Technical Report
·
Thu Feb 28 23:00:00 EST 1985
·
OSTI ID:5949736
I. Kinetic and mechanistic study of the (4+4) dimerization of 2,3-dimethylene-2,3-dihydrofuran. II. Preparation of 2,3-dimethylene-2,3-dihydrobenzo(B)furan by the flash vacuum pyrolysis of 2-methyl-3-benzo(B)furylmethyl benzoate. III. Reaction of 2,3-dimethylene-2,3-dihydrofuran with triplet oxygen
Thesis/Dissertation
·
Mon Dec 31 23:00:00 EST 1984
·
OSTI ID:6036372
(4 + 4) dimerization of 2,3-dimethylene-2,3-dihydrofuran: secondary deuterium kinetic isotope effect evidence of a two-step mechanism
Journal Article
·
Wed Jul 09 00:00:00 EDT 1986
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5585181