Titania-silica mixed oxides. V. Effect of sol-gel and drying conditions on surface properties
- Swiss Federal Inst. of Technology, Zurich (Switzerland)
Mesoporous titania-silica aerogels have been prepared by an alkoxide-sol-gel process with ensuing supercritical drying which involved either semicontinuous extraction using supercritical CO{sub 2} or transferring the solution-sol-gel liquid directly into the super-critical state. Surface properties of these materials were compared to those of conventionally dried titania-silica xerogel. The influence of several important preparation parameters (hydrolysis route, Ti-content, and drying method) on surface properties of the gels were investigated by temperature-programmed reaction and desorption (TPRD) of isopropanol and X-ray photoelectron spectroscopy (XPS). The information gained by these surface-sensitive methods was interpreted in the light of previous bulk structural investigations, i.e., X-ray diffraction, FTIR, FTRaman, and UV-vis spectroscopy. Up to 723 K, three TPRD peaks were identified and assigned to the different surface species in titania-silica mixed oxides found in previous structural investigations: inactive silica domains, titania domains, and highly dispersed Ti in silica (Si-O-Ti linkages). The Ti-containing surface species catalyzed dehydration of isopropanol to propene at different temperatures. Depending on the dispersion and nature of titanium oxo species on the surface of the titania-silica sol-gel mixed oxides (Si-O-Ti heteroconnectivity), significant differences in the reaction-desorption profiles were observed. All titania-silica gels showed enrichment of the surface with silica. This behavior strongly depended on the drying procedure applied. Low-temperature supercritical drying and evaporative drying yielded higher titania surface concentration (lower Si enrichment) compared to high-temperature supercritical drying. 23 refs., 8 figs.
- OSTI ID:
- 468694
- Journal Information:
- Journal of Catalysis, Journal Name: Journal of Catalysis Journal Issue: 2 Vol. 164; ISSN 0021-9517; ISSN JCTLA5
- Country of Publication:
- United States
- Language:
- English
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