IRRADIATION OF MIXTURE OF PERCHLORO-ETHYLENE AND ALCOHOLS (in Japanese)
Journal Article
·
· Proc. Japan Conf. Radioisotopes
OSTI ID:4684341
The reaction between perchloroethylene and alcohols is not producible by the methods of photochemistry or by the use of peroxide radical-forming reagents, but it is readily produced by gamma irradiation. The main reaction is the 1 : 1 addition reaction. Various chloric alcohols of the 1 :1 addition products are separable. A mixture of 1:4 mole ratio of perchlorcethylene and alcohols is sealed in an ampule, and irradiated at dose rates of 0.16 x 10/sup 5/ to 3 x 10/ sup 5/ r/hr with gamma rays. The unreacted perchloroethylene and alcohol are distilled after irradiation and the residue is distilled in vacuum, by which means a transparent, viscous residual oil having a moldy odor is obtained. The yields using various alcohols, and the reaction rates of perchloroethylene, are tabulated. (T.F.H.)
- Research Organization:
- Government Industrial Research Inst., Nagoya
- NSA Number:
- NSA-17-029903
- OSTI ID:
- 4684341
- Journal Information:
- Proc. Japan Conf. Radioisotopes, Journal Name: Proc. Japan Conf. Radioisotopes Vol. Vol: 4th
- Country of Publication:
- Country unknown/Code not available
- Language:
- Japanese
Similar Records
Two stage production of ether from tertiary alcohol
SYNTHESIS OF SEVERAL TERTIARY ALCOHOLS FROM PROPANOL-2 AND ETHYLENE BY $gamma$-RAY IRRADIATION
Ditertiary butyl peroxide recovery
Patent
·
Tue Jul 27 00:00:00 EDT 1993
·
OSTI ID:6411782
SYNTHESIS OF SEVERAL TERTIARY ALCOHOLS FROM PROPANOL-2 AND ETHYLENE BY $gamma$-RAY IRRADIATION
Journal Article
·
Sat Dec 31 23:00:00 EST 1960
· Proc. Japan Conf. Radioisotopes
·
OSTI ID:4692772
Ditertiary butyl peroxide recovery
Patent
·
Mon Mar 06 23:00:00 EST 1989
·
OSTI ID:6113029