Hydrogen abstraction in the neutral molecular cluster of benzophenone and hydrogen donors formed in a supersonic free jet expansion
Journal Article
·
· Journal of Physical Chemistry
- Tokyo Institute of Technology, Ohokayama, Meguro (Japan)
This paper discusses how benzophenone undergoes photoreduction to form benzophenone ketyl radical by an intracellular reaction in the benzophenone 1,4-cyclohexadiene mixed expansion in a supersonic free jet expansion. No ketyl radical fluorescence is observed when triethylamine, 2-propanol, or ethanol is the hydrogen donor; thus the normal molecular cluster activity depends on the nature of the hydrogen donor. 36 refs., 5 figs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 468060
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 16 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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