ORGANIC SALTS OF LANTHANIDE ELEMENTS. I. PREPARATION OF TRI-ACYLATES OF LANTHANUM AND CERIUM(III) FROM AQUEOUS SOLUTIONS

Journal Article · Fri Mar 01 04:00:00 EST 1963 · Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron

DOI:https://doi.org/10.1016/0022-1902(63)80009-3· OSTI ID:4677937

Misra, S N; Misra, T N; Mehrotra, R C

Tri-acylates of lanthanum and cerium (III) are quantitatively precipitated by the reaction of their nitrates or chlorides with excess of sodium soaps (laurate, palmitate, stearate) in aqueous solutions. These salts are not hydrolysed by water and are soluble in hot benzene from which pure samples may be crystallized. Molecular weight measurements show them to be monomeric in benzene. Viscosities of their benzene solutions were measured and their thermogravimetric behavior was also investigated. Attempts to prepare mixed chloride or nitrate salts were unsuccessful. (auth)

• Research Organization: Gorakhpur Univ., India
• NSA Number: NSA-17-025095
• OSTI ID: 4677937
• Journal Information: Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron, Journal Name: Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron Vol. Vol: 25; ISSN JINCA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

BENZENE
CERIUM COMPOUNDS
CERIUM NITRATES
CHEMICAL REACTIONS
CHEMISTRY
CRYSTALLIZATION
LANTHANUM COMPOUNDS
LANTHANUM NITRATES
LAURIC ACID
ORGANIC ACIDS
PALMITIC ACID
PRECIPITATION
PREPARATION
SODIUM COMPOUNDS
SOLUBILITY
SOLUTIONS
STEARIC ACID
VISCOSITY
WATER