COMPLEX FORMATION BY N-SUBSTITUTED ACETOACETAMIDES. I. ACID DISSOCIATION CONSTANTS AND STABILITY CONSTANTS OF THE BERYLLIUM COMPLEXES
Journal Article
·
· Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron
A number of derivatives of acetoacetamide were examined as chelating agents. Using the glass electrode, the acid dissociation constants were determined in 50 per cent dioxane (v/v) and the stability constants of their beryllium complexes measured. The variation of pK/sub a/ with N-substituent is interpreted in terms of electronic and steric effects. The variation of stability constants shows that the chelating power is related to the basic strength of the enolate ion for a series of structurally similar compounds. (auth) interfacial turbulence, arising probably from the Marangoni effect. (auth)
- Research Organization:
- Derby and District Coll. of Tech., Derby, Eng.
- NSA Number:
- NSA-17-025103
- OSTI ID:
- 4677901
- Journal Information:
- Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron, Journal Name: Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron Vol. Vol: 25; ISSN JINCA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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