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Title: Bench-scale demonstration of hot-gas desulfurization technology. Quarterly report, October 1 - December 31, 1994

Technical Report ·
DOI:https://doi.org/10.2172/466812· OSTI ID:466812

The U.S. Department of Energy (DOE), Morgantown Energy Technology Center (METC), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal gas) streams of integrated gasification combined-cycle (IGCC) power systems. The programs focus on hot-gas particulate removal and desulfurization technologies that match or nearly match the temperatures and pressures of the gasifier, cleanup system, and power generator. The work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents which can reduce the sulfur in coal gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn{sub 2}TiO{sub 4} or ZnTiO{sub 3}), formed by a solid-state reaction of zinc (ZnO) and titanium dioxide (TiO{sub 2}), is currently one of the leading sorbents. This report summarizes the highlights and accomplishments of the October slipstream test run of the Zinc Titanate Fluid Bed Desulfurization/Direct Sulfur Recovery Process (ZTFBD/DSRP) Mobile Laboratory at the Department of Energy`s Morgantown Energy Technology Center. Although the run had to be shortened due to mechanical problems with METC`s gasifier, there was sufficient on-stream time to demonstrate highly successful operation of both the zinc titanate fluid bed desulfurization and the DSRP with actual coal gas.

Research Organization:
USDOE Morgantown Energy Technology Center (METC), WV (United States); Research Triangle Inst., Research Triangle Park, NC (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Fossil Energy, Washington, DC (United States)
DOE Contract Number:
AC21-93MC30010
OSTI ID:
466812
Report Number(s):
DOE/MC/30010-5354; ON: DE97051613
Resource Relation:
Other Information: PBD: [1994]
Country of Publication:
United States
Language:
English