Chemical Shifts in Xenon Fluorides
Journal Article
·
· Journal of Chemical Physics
The consistency of proposed bonding schemes with the chemical shifts observed in nuclear magnetic resonance studies of the XeFn (N = 2,4,6) compounds was investigated. Equations were developed for calculating chemical shifts based on a molecular description of XeFn compounds that postulates the formation of highly ionic bonds involving primarily the 2 p orbitals of fluorine and the 5 p orbitals of xenon. Comparison with experimental data showed that molecular mode is consistent with the main features of the observations. (M.C.G.)
- Research Organization:
- Columbia Univ., New York
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-17-035752
- OSTI ID:
- 4666959
- Journal Information:
- Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 6 Vol. 39; ISSN JCPSA6; ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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