High-Resolution F¹⁹ and Xe¹²⁹ Magnetic Double Resonance Spectrum of XeOF₄

Journal Article · Tue Jan 01 00:00:00 EST 1963 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.1733638· OSTI ID:4658254

Brown, Thomas H.; Whipple, E. B.; Verdier, Peter H.

A method is described for obtaining high resolution F¹⁹ and Xe¹²⁹ magnetic double resonance spectrum of XeOF₄. The F¹⁹ spectrum was observed with a standard highresolution spectrometer operating at fixed frequencies of 56.442 and 15.000 Mc. Double resonance experiments were carried out by observing the fluorine resonances at 56.442 Mc while injecting a variable tickling frequency in the vicinity of 18.7 Mc across the transmitter coil of the spectrometer probe. The tickling field was obtained initially from a modified radiotransmitter driven at 8.35 Mc either by a signal generator or by a variable- frequency r-f unit.

• Research Organization: Union Carbide Research Inst., Tarrytown, N.Y.
• Sponsoring Organization: USDOE
• NSA Number: NSA-17-033902
• OSTI ID: 4658254
• Journal Information: Journal of Chemical Physics, Vol. 38, Issue 12; Other Information: Orig. Receipt Date: 31-DEC-63; ISSN 0021-9606
• Publisher: American Institute of Physics (AIP)
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
FLUORINE 19
FREQUENCY
GENERATORS
INSTRUMENTS
MAGNETIC FIELDS
MAGNETIC RESONANCE
MEASURED VALUES
MICROWAVES
RESOLUTION
SPECTRA
SPECTROMETERS
SPECTROSCOPY
XENON 129
XENON FLUORIDES
XENON OXIDES