DISSOCIATION CONSTANTS OF SOME BARIUM, EUROPIUM, AND HEXAAMMINECOBALT ION- PARIS BY USE OF SPARINGLY SOLUBLE IODATES CONTAINING RADIOTRACERS

Journal Article · Sat Jun 01 00:00:00 EDT 1963 · Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.

DOI:https://doi.org/10.1039/jr9630003343· OSTI ID:4657973

Laurie, S H; Monk, C B

The solubilities of barium iodate containing I/sup 131/, europium iodate containing Eu(/sup 152+154)/, and hexamnainecobalt iodate containing Co/sup 60/ in salt solutions of ion-pairing ligands were measured by relating the count rates to the solubilities in H/sub 2/O at 25 deg C as found by volumetric estimation of the iodate concentrations. The results, combined with Davies's general activity coefficient expression, were used to calculate the corresponding dissociation constants. It was also demonstrated that such calculations may be made with only rough estimates of the solubilities in H/sub 2/O combined with the relative count rates of the aqueous salt solutions. (auth)

• Research Organization: University College of Wales, Aberystwyth, Eng.
• NSA Number: NSA-17-033916
• OSTI ID: 4657973
• Journal Information: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc., Journal Name: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.; ISSN JCSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

AMMONIUM COMPOUNDS
BARIUM COMPOUNDS
CHEMISTRY
COBALT 60
COBALT COMPOUNDS
COMPLEXES
DECOMPOSITION
ELECTROCHEMISTRY
EUROPIUM 152
EUROPIUM 154
EUROPIUM COMPOUNDS
IODIC ACID
IODINE 131
IONS
MINERAL ACIDS
NUMERICALS
QUALITATIVE ANALYSIS
QUANTITATIVE ANALYSIS
QUANTITY RATIO
RADIOCHEMISTRY
SALTS
SOLUBILITY
SOLUTIONS
TEMPERATURE
THERMODYNAMICS
TITRATION
TRACER TECHNIQUES
WATER