GAS-PHASE RADIOLYSIS OF PROPANE. EFFECT OF PRESSURE AND ADDED INERT GASES
Technical Report
·
OSTI ID:4657214
>The direct and inert-gas radiolysis, as well as the vacuum ultraviolet photolysis of CD/sub 3/CH/sub 2/CD/sub 3/, CH/sub 3/CD/sub 2/CH/ sub 3/ and C/sub 3/H/sub 3/ + C/sub 3/D/sub 8/ mixtures were investigated in the presence o f radical scavengers. The major conclusions are: (a) at atmospheric pressures, neutral propane decomposition contributes to the observed products although to a lesser extent than parent ion decompositions; (b) a variation in pressure has a pronounced effect on the fragmentation of the parent ion; (c) the hydrogen atoms in the ethyl ion are randomized in the direct as well as in the inert-gas sensitized radiolysis; (d) rearrangement in the parent ion is of minor importance in the radiolysis; (e) although the formation of propylene is related to the propyl ion, it is not necessarily produced by the neutralization of this ion. (auth)
- Research Organization:
- National Bureau of Standards, Washington, D.C.
- NSA Number:
- NSA-17-039099
- OSTI ID:
- 4657214
- Report Number(s):
- CONF-224-6
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
Similar Records
RADIOLYSIS OF ETHANE-1,1,1-d$sub 3$
EFFECT OF PRESSURE IN THE RADIOLYSIS AND PHOTOLYSIS OF METHANE
VAPOR PHASE $gamma$-RADIOLYSIS OF AZOMETHANE
Journal Article
·
Fri Jun 01 00:00:00 EDT 1962
· Journal of Chemical Physics (U.S.)
·
OSTI ID:4827501
EFFECT OF PRESSURE IN THE RADIOLYSIS AND PHOTOLYSIS OF METHANE
Journal Article
·
Tue Mar 31 23:00:00 EST 1964
· Journal of Chemical Physics (U.S.)
·
OSTI ID:4041725
VAPOR PHASE $gamma$-RADIOLYSIS OF AZOMETHANE
Journal Article
·
Mon May 01 00:00:00 EDT 1961
· Journal of Physical Chemistry (U.S.)
·
OSTI ID:4052868