Rearrangement Studies With C 14 : XV. Ethyl-2-C 14 Iodide fron the Irradiation of Ethyl-1-C 14 Iodide with Cobalt-60 Gamma Rays
Journal Article
·
· Canadian Journal of Chemistry
Irradiation of ethyl-1-C/sup 14/ iodide gave ethyl-2-C/sup 14/ iodide with G/sub r/ of 0.27 to 0.28 for samples that were either deaerated or not deaerated. Addition of 1% by weight of iodine before irradiation decreased the extent of rearrangement to nearly zero. The occurrence of 1,2-hydrogen shifts in ethyl radicals outside of the spurs, which may be susceptible to scavenger action, is suggested as a possible path which would lead to the ethyl-2-C/sup 14/ iodide.
- Research Organization:
- Univ. of Saskatchewan, Saskatoon
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-17-035874
- OSTI ID:
- 4655049
- Journal Information:
- Canadian Journal of Chemistry, Journal Name: Canadian Journal of Chemistry Journal Issue: 9 Vol. 41; ISSN 0008-4042
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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