RADIOLYSIS OF THIOPHENOL IN BENZENE

Journal Article · Mon Jan 01 04:00:00 EST 1962 · Ann. Rept. Radiation Center Osaka Prefect

OSTI ID:4651857

Ando, W; Sugimoto, K; Oae, S

The radiolysis of thiophenol in benzene solution was studied. Thiophenol is oxidized to diphenyl disulfide as the radiation energy absorbed in the benzene is transferred to the thiophenol. The effects of the initial concentration of thiophenol and the radiation doses were measured directly, and the first order rate constant was calculated. The relative stability of the S-H and C-S bonds was about 1:200. Radiolysis of diphenyl disulfide or hydrogen sulfide in benzene was found to form thiophenol. (P.C.H.)

• Research Organization: Originating Research Org. not identified
• NSA Number: NSA-17-033977
• OSTI ID: 4651857
• Journal Information: Ann. Rept. Radiation Center Osaka Prefect, Journal Name: Ann. Rept. Radiation Center Osaka Prefect Vol. Vol: 3
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ABSORPTION
BENZENE
BINDING ENERGY
CARBON
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
ENERGY
HYDROGEN
HYDROGEN SULFIDES
MEASURED VALUES
MOLECULES
NUMERICALS
ORGANIC SULFUR COMPOUNDS
OXIDATION
PHENOLS
PHENYL RADICALS
QUANTITY RATIO
RADIATION CHEMISTRY
RADIATION DOSES
RADIATIONS
RADIOLYSIS
REACTION KINETICS
SOLUTIONS
STABILITY
SULFIDES
SULFUR
THIOPHENOLS