RADIOLYSIS OF BENZENE AND 1,3,5-OCTATRIENE-7-OL IN SOLID SOLUTION AT 77 K (in French)
1,3-cyclohexadiene, 5-hydroxyethyl-1,3-cyclohexadiene, and 6-phenyl-5- hydroxyethyl-1,3-cyclohexaethanol were found in solutions of benzene--ethanol irradiated by x or gamma rays at 77 deg K and then heated to room temperature. These compounds are formed by the addition to benzene of radicals formed in the radiolysis of the solvent. Analogous results were observed for solutions of benzene in methylcyclohexane or in methylcyclohexane-isopentane mixtures. An attempt was made to show an opening of the benzene cycle analogous to that observed in the photolysis of solid solutions where a linear substituted triene is formed as the principal product. However, the radiolysis decomposition of 1,3,5-octatriene-7-ol in solid solution at 77 deg K shows that the opening of the benzene cycle is not easily detectable. (tr-auth)
- Research Organization:
- Faculte des Sciences, Orsay, France
- NSA Number:
- NSA-17-034007
- OSTI ID:
- 4651535
- Journal Information:
- Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides, Vol. Vol: 60; Other Information: Orig. Receipt Date: 31-DEC-63
- Country of Publication:
- Country unknown/Code not available
- Language:
- French
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Related Subjects
ALCOHOLS
ALKENES
AROMATICS
BENZENE
CHEMICAL REACTIONS
CRYSTALS
CYCLOALKANES
CYCLOALKENES
ETHANOL
ETHYL RADICALS
FREE RADICALS
GAMMA RADIATION
HEATING
HEXANE
HYDROXIDES
IRRADIATION
ISOMERS
LOW TEMPERATURE
MEASURED VALUES
METHYL RADICALS
MIXING
OCTANE
OPERATION
PENTANE
PHENYL RADICALS
PHOTOCHEMISTRY
RADIATION CHEMISTRY
RADIATION EFFECTS
SENSITIVITY
SOLID SOLUTIONS
SOLUTIONS
SOLVENTS
X RADIATION