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GEM-BIS(DISUBSTITUTEDPHOSPHINYL)AKLANES. III. CYRSTALLINE COMPLEXES OF BIS(DI-2-ETHYLBUTLYPHOSPHINYL)METHANE WITH URANIUM(VI) NITRATE AND WITH THORIUM NITRATE

Technical Report ·
OSTI ID:4638826
;

Bis (di -2-ethylbutylphosphinyl)methane, EBDPM, forms complexes with uranium(VI) nitrate and thorium(IV) nitrate in which EBDPM acts as a bidentate ligand and the nitrato groups appear to be coordinated. The complex with uranium(VI) is a monomer, UO/sub 2/(NO/sub 3/)/sub 2/(EBDPM), whole the complex with thorium is a dimer, (Th(NO/sub 3/)/sub 4/!/sub 2/(EBDPM)/sub 3/. Both complexes are of high thermal stability. (auth)

Research Organization:
Ames Lab., Ames, Iowa
DOE Contract Number:
W-7405-ENG-82
NSA Number:
NSA-17-035685
OSTI ID:
4638826
Report Number(s):
IS-560
Country of Publication:
United States
Language:
English

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Related Subjects

ALKANES
CHEMISTRY
COMPLEXES
CRYSTALS
ETHYL RADICALS
METHANE
ORGANIC PHOSPHORUS COMPOUNDS
STABILITY
TEMPERATURE
THORIUM COMPLEXES
THORIUM NITRATES
URANIUM COMPLEXES
URANIUM NITRATES