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INFRARED SPECTRA OF OXYORTHOSILICATES OF RARE EARTH ELEMENTS (in Russian)

Journal Article · · Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (U.S.S.R.) For English translation see Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.)
OSTI ID:4638570

Infrared spectra of Ln(SiO/sub 4/)O (Ln = Dy, Eu, Gd, La, Lu, Nd, Sc, Sm, Y, and Yb) separated the pyro- and orthosilicate compounds into three groups according to their constitution diagrams. Spectra of certain oxyorthosilicates exhibited bond oscillations in the Lm--O--Ln bond incorporating O/sup 2-/. The bonds covalence is increasing from La yields Lu (and La yields Y yields Sc). (R.V.J.)

Research Organization:
Inst. of Silicate Chemistry, Academy of Sciences, USSR
NSA Number:
NSA-17-035725
OSTI ID:
4638570
Journal Information:
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (U.S.S.R.) For English translation see Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), Journal Name: Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (U.S.S.R.) For English translation see Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.) Vol. Vol: No. 7; ISSN IASKA
Country of Publication:
Country unknown/Code not available
Language:
Russian

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