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Title: Metallic glass alloys of Zr, Ti, Cu and Ni

Abstract

At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3} K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM{sub 1{minus}x}Ti{sub x}){sub a} Cu{sub b} (Ni{sub 1{minus}y}Co{sub y}){sub c} wherein x is from 0.1 to 0.3, y{center_dot}c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, andmore » c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b. 2 figs.« less

Inventors:
; ;
Publication Date:
Research Org.:
California Institute of Technology
OSTI Identifier:
462863
Patent Number(s):
US 5,618,359/A/
Application Number:
PAN: 8-569,276
Assignee:
California Inst. of Tech., Pasadena, CA (United States) PTO; SCA: 360101; PA: EDB-97:061710; SN: 97001767258
DOE Contract Number:  
FG03-86ER45242
Resource Type:
Patent
Resource Relation:
Other Information: PBD: 8 Apr 1997
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; METALLIC GLASSES; FABRICATION; ZIRCONIUM ALLOYS; TITANIUM ALLOYS; NICKEL ALLOYS; COPPER ALLOYS; HAFNIUM ALLOYS; COBALT ALLOYS; CHEMICAL COMPOSITION; DESIGN

Citation Formats

Lin, X., Peker, A., and Johnson, W.L.. Metallic glass alloys of Zr, Ti, Cu and Ni. United States: N. p., 1997. Web.
Lin, X., Peker, A., & Johnson, W.L.. Metallic glass alloys of Zr, Ti, Cu and Ni. United States.
Lin, X., Peker, A., and Johnson, W.L.. Tue . "Metallic glass alloys of Zr, Ti, Cu and Ni". United States.
@article{osti_462863,
title = {Metallic glass alloys of Zr, Ti, Cu and Ni},
author = {Lin, X. and Peker, A. and Johnson, W.L.},
abstractNote = {At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3} K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM{sub 1{minus}x}Ti{sub x}){sub a} Cu{sub b} (Ni{sub 1{minus}y}Co{sub y}){sub c} wherein x is from 0.1 to 0.3, y{center_dot}c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b. 2 figs.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {4}
}