Kinetics and mechanism of reactions of some transition metal complexes containing metal--carbon bonds
- Iowa State Univ., Ames, IA (United States)
Mercury (II) rapidly reacts with cobalt complexes of the type CH3Co(L)H2O, where L is a Schiff base, to form methylmercury (II) and Co(L) (H2O)2+. Kinetic measurements were made on these reactions which follow a second-order rate expression after correction for a reversible protonation reaction. The reactivity of the series of cobalt complexes is discussed in therms of dπ-pπ bonding in the methylcobalt (III) complex. The reaction of SCN- with Cr (H2O)R2+ (R=CH2Cl, CHCl2) to form Cr (H2O)4R(NCS)+ has also been investigated.
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- US Atomic Energy Commission (AEC)
- DOE Contract Number:
- W-7405-ENG-82
- NSA Number:
- NSA-27-016878
- OSTI ID:
- 4611617
- Report Number(s):
- IS-T--527
- Country of Publication:
- United States
- Language:
- English
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