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13CO substitution in Mn2(CO)10 and Re2(CO)10

Journal Article · · Journal of Inorganic and Nuclear Chemistry
;

By means of 13CO-enriched Mn(CO)5Br and 13CO-enriched Re(CO)5Cl, isotopically enriched species of Mn2(CO)10 and Re2(CO)10 have been prepared. I.R. and Raman spectra in the CO-stretching region have been obtained for these molecules and detailed assignments of the CO stretching modes are made. Force constants are calculated using a CO-factored force field. The results indicate that some of the assumption of the Cotton-Kraihanzel force field are valid for these compounds.

Research Organization:
Originating Research Org. not identified
NSA Number:
NSA-27-005020
OSTI ID:
4595756
Journal Information:
Journal of Inorganic and Nuclear Chemistry, Journal Name: Journal of Inorganic and Nuclear Chemistry Journal Issue: 12 Vol. 34; ISSN 0022-1902
Country of Publication:
United States
Language:
English

References (9)

Vibrational Spectra and Bonding in Metal Carbonyls. I. Infrared Spectra of Phosphine-substituted Group VI Carbonyls in the CO Stretching Region journal December 1962
The reaction of carbon monoxide with HRe3(CO)14; a chemical route for stereospecific 13CO labelling of Re2(CO)10 journal March 1966
Reassignment of the infrared-inactive C–O stretching frequencies of decacarbonyldimanganese journal January 1969
The vibrational spectra of rhenium carbonyl and rhenium carbonyl iodide journal January 1967
A Raman spectroscopic study of dimanganese and dirhenium decacarbonyls journal January 1971
Derivatives of Technetium Carbonyl. Synthesis and Properties of the Carbonyl Halides and the Pentacarbonyl Hydride journal November 1962
Analysis of the Infrared Spectra of Metal Carbonyls journal October 1967
Spectroscopic studies of isotopically substituted metal carbonyls. I. Vibrational analysis of metal pentacarbonyl halides journal June 1967
Vibrational Spectra and Bonding in Metal Carbonyls. IV. CO and Re-Re Stretching Modes in the Decacarbonyls of Rhenium and Manganese journal September 1965

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Related Subjects

N40220* --Chemistry--Inorganic
Organic
& Physical Chemistry--Isotopic Effects