Laser Raman Spectrum of Crystalline Cyclopentane-d and -d10

Schettino, V.; Marzocchi, M. P.

doi:10.1063/1.1678052

Laser Raman Spectrum of Crystalline Cyclopentane-d and -d₁₀

Journal Article · Tue Nov 14 23:00:00 EST 1972 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.1678052· OSTI ID:4590719

Schettino, V. ^[1]; Marzocchi, M. P. ^[1]

Univ. di Firenze (Italy)

Here, the laser Raman spectrum of the crystal form III of cyclopentane and cyclopentane-d₁₀ has been measured at 85°K. The frequencies and splittings of the internal modes and the number of observed lattice modes are consistent with the crystal structure deduced from the analysis of the infrared spectrum. Some details of the vibrational assignment are discussed, and consistency with observed gas phase heat capacities is checked.

Research Organization:: Univ. di Firenze (Italy)

Sponsoring Organization:: US Atomic Energy Commission (AEC)

NSA Number:: NSA-27-005037

OSTI ID:: 4590719

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 10 Vol. 57; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: Italy

Language:: English

References (5)

Cyclopentane: Molecular vibrational analysis Kruse, F. H.; Scott, D. W. Journal of Molecular Spectroscopy, Vol. 20, Issue 3 https://doi.org/10.1016/0022-2852(66)90030-0	journal	July 1966
Vibrational analysis of the n-paraffins—II Schachtschneider, J. H.; Snyder, R. G. Spectrochimica Acta, Vol. 19, Issue 1 https://doi.org/10.1016/0371-1951(63)80096-X	journal	January 1963
X-Ray Investigation of Crystalline Cyclopentane and Neohexane¹ Post, Benjamin; Schwartz, Robert S.; Fankuchen, I. Journal of the American Chemical Society, Vol. 73, Issue 11 https://doi.org/10.1021/ja01155a028	journal	November 1951
Consistent Force Field for Calculations of Conformations, Vibrational Spectra, and Enthalpies of Cycloalkane and n ‐Alkane Molecules Lifson, S.; Warshel, A. The Journal of Chemical Physics, Vol. 49, Issue 11 https://doi.org/10.1063/1.1670007	journal	December 1968
Infrared Spectra of Crystalline Cyclopentane and Cyclopentane-d10 Schettino, V.; Marzocchi, M. P.; Califano, S. The Journal of Chemical Physics, Vol. 51, Issue 12 https://doi.org/10.1063/1.1671944	journal	December 1969

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Laser Raman Spectrum of Crystalline Cyclopentane-d and -d10

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References (5)

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Laser Raman Spectrum of Crystalline Cyclopentane-d and -d₁₀