Building of 2D sheet of tetrakis(methylthio)tetrathiafulvalenes coordinating to copper(I) halides with zigzag and helical frames and the 3D network through the S{hor_ellipsis}S contacts

Journal Article · Wed May 10 00:00:00 EDT 1995 · Inorganic Chemistry

DOI:https://doi.org/10.1021/ic00114a032· OSTI ID:458753

Munakata, Megumu; Kuroda-Sowa, Takayoshi; Maekawa, Masahiko ^[1]

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1. Kinki Univ., Osaka (Japan); and others

X-ray diffraction was used to structurally characterize three copper (I) complexes with tetrakis(methylthio)tetrathiafulvalene (TMT-TTF), [Cu{sub 2}({mu}-X){sub 2}({mu}-TMT-TTF)]{sub {infinity}} (X = Cl, 1; X = Br, 2; X = I, 3). The molecular and crystal structures are reported.

• Sponsoring Organization: USDOE
• OSTI ID: 458753
• Journal Information: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 10 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
40 CHEMISTRY
COPPER COMPLEXES
CRYSTAL STRUCTURE
ELECTRIC CONDUCTIVITY
HETEROCYCLIC COMPOUNDS
MONOCLINIC LATTICES
ORGANIC SULFUR COMPOUNDS