Water-soluble organometallic compounds. 2. Catalytic hydrogenation of aldehydes and olefins by new water-soluble 1,3,5-Triaza-7-phosphaadamantane complexes of ruthenium and rhodium
- Texas A&M Univ., College Station, TX (United States)
The authors describe the chemical preparation of water-soluble phosphine complexes of ruthenium (II) and rhodium (I). The complex RuCl{sub 2}(PTA){sub 4} (2a) and its protonated analog RuCl{sub 2}(PTA){sub 4}{center_dot} 2HCl (2b) and the cis-bis-(phosphine) complex RhCl(PTA){sub 2}{center_dot} 2HCl, derived form the protonation of RhCl(PTA){sub 3} by HCl were characterized by X-ray crystallography. 2a is catalytically active for the conversion of unsaturated aldehydes to unsaturated alcohols and RhCl(PTA){sub 3} catalyzes olefin hydrogenation. 14 refs., 2 figs., 1 tab.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 458719
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 6 Vol. 11; ISSN ORGND7; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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