Experimental study of multiple steady states in homogeneous azeotropic distillation

Journal Article · Sat Mar 01 04:00:00 EST 1997 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/ie960522g· OSTI ID:458458

Guettinger, T E; Dorn, C; Morari, M ^[1]

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1. Swiss Federal Inst. of Technology, Zuerich (Switzerland). Automatic Control Lab.

Bekiaris et al. (1993) explained the existence of multiple steady states in homogeneous ternary azeotropic distillation, on the basis of the analysis of the case of infinite reflux and infinite column length (infinite number of trays). They showed that the predictions of multiple steady states for such infinite columns have relevant implications for columns of finite length operated at finite reflux. In this article, experiments are described for the ternary homogeneous system methanol-methyl butyrate-toluene which demonstrate the existence of multiple steady states (output multiplicities) caused by the vapor-liquid-equilibrium. The experiments on an industrial pilot column show two stable steady states for the same feed flow rate and composition and the same set of operating parameters. The measurements are in excellent agreement with the predictions obtained for infinite columns using the {infinity}/{infinity} analysis tool as well as with stage-by-stage simulation results. These experiments represent the first published study reporting evidence for the predictions and simulations by various researchers showing that type of output multiplicities in distillation.

• Sponsoring Organization: USDOE
• OSTI ID: 458458
• Journal Information: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 3 Vol. 36; ISSN IECRED; ISSN 0888-5885
• Country of Publication: United States
• Language: English

Related Subjects

10 SYNTHETIC FUELS
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
AZEOTROPE
CARBOXYLIC ACID ESTERS
DISTILLATION
DISTILLATION EQUIPMENT
FLUID MECHANICS
METHANOL
STEADY-STATE CONDITIONS
TOLUENE