Ab initio study of the formation of H{sub 2}B=NH{sub 2} from NH{sub 3} and B{sub 2}H{sub 6}
Journal Article
·
· Journal of Physical Chemistry
- Auburn Univ., AL (United States)
The reaction of ammonia and diborane to form aminoborane is studied. The initial step yields NH{sub 3}(BH{sub 3}){sub 2}. Then H{sub 2} elimination occurs either bimolecularly or by catalysis in the observed reaction. The potential energy surface and vibrational frequencies are also calculated. 26 refs., 3 figs., 8 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 457780
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 13 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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