Matrix reactions of SiH{sub 4} and GeH{sub 4} with F{sub 2}. Infrared spectra of several HF product complexes
Journal Article
·
· Journal of Physical Chemistry
- Univ. of Virginia, Charlottesville, VA (United States)
In this paper, condensation of SiH{sub 4} and GeH{sub 4} with F{sub 2} yields various product complexes. H-F vibrations in these complexes suggest that F is more basic in GeH{sub 3}F than SiH{sub 3}F since Ge is more electropositive than Si. 35 refs., 13 figs., 5 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 457765
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 13 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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