Steady-state and time-resolved direct detection EPR spectra of fullerene triplets in liquid solution and glassy matrices. Evidence for a dynamic Jahn-Teller effect in triplet C{sub 60}
Journal Article
·
· Journal of Physical Chemistry
- Univ. of Chicago, IL (United States); and others
Steady-state and time-resolved EPR spectroscopy of UV-irradiated C{sub 60}-methylcyclohexane solutions reveal evidence of a dynamic Jahn-Teller effect in triplet C{sub 60} in this paper. This is attributed to a very rapid interchange of the magnetic axes by pseudorotation. This is supported by other spectra of methylcyclohexane glasses and the different behavior of C{sub 70}. 14 refs., 4 figs., 1 tab.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 457756
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 13 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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