High-Rydberg and autoionizing states of HCO
Conference
·
OSTI ID:456907
- Purdue Univ., West Lafayette, IN (United States)
Double-resonant transitions through the 3p{pi} Rydberg state of HCO state-select autoionizing series converging to specific vibrationally excited thresholds of HCO+. Extrapolation of series, combined with existing knowledge of the vibrational structure of the cation, provides the first accurate determination of the adiabatic ionization potential of HCO. Lineshapes and intensities of resonances reflect mode-specific trends in Rydberg-core coupling dynamics.
- OSTI ID:
- 456907
- Report Number(s):
- CONF-9506113--
- Country of Publication:
- United States
- Language:
- English
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