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Microstructural development of silicon carbide containing large seed grains

Journal Article · · Journal of the American Ceramic Society
 [1];  [2];  [3]
  1. Seoul City Univ. (Korea, Republic of). Dept. of Materials Science and Engineering
  2. National Inst. for Research in Inorganic Materials, Ibaraki (Japan)
  3. Denki Kagaku Kogyo Co., Tokyo (Japan). Research Center

Fine ({approximately}0.1 {micro}m) {beta}-SiC powders, with 3.3 wt% large ({approximately}0.44 {micro}m) {alpha}-SiC or {beta}-SiC particles (seeds) added, were hot-pressed at 1,750 C and then annealed at 1,850 C to enhance grain growth. Microstructural development during annealing was investigated using image analysis. The introduction of larger seeds into {beta}-SiC accelerated the grain growth of elongated large grains during annealing, in which no appreciable {beta}{yields}{alpha} phase transformation occurred. The growth of matrix grains in materials with {beta}-SiC seeds was slower than that in materials with {alpha}-SiC seeds. The material with {beta}-SiC seeds, which was annealed at 1,850 C for 4 h, had a bimodal microstructure of small matrix grains and large elongated grains. In contrast, the material with {alpha}-SiC seeds, also annealed at 1,850 C for 4 h, had a uniform microstructure consisting of elongated grains. The fracture toughnesses of the annealed materials with {alpha}-SiC and {beta}-SiC seeds were 5.5 and 5.4 MPa{center_dot}m{sup 1/2}, respectively. Such results suggested that further optimization of microstructure should be possible with {beta}-SiC seeds, because of the remnant driving force for grain growth caused by the bimodal microstructure.

Sponsoring Organization:
USDOE
OSTI ID:
455160
Journal Information:
Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 1 Vol. 80; ISSN 0002-7820; ISSN JACTAW
Country of Publication:
United States
Language:
English

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