An FTIR spectroscopic study of the selective oxidation of nitrosobenzene to nitrobenzene by metal oxides
- Leiden Univ. (Netherlands)
Reactions of nitrosobenzene on the surfaces of metal oxides has been studied using IR spectroscopy. The major products of are nitrobenzene and azoxybenzene. Nitrosobenzene is found to be coordinated intact to metal cations by {sigma}-N as well as {sigma}-O bonds. Comparisons to the bonding modes of nitrosobenzene on metal oxides and nitroso ligands of organometallic complexes indicate a link between both chemistries. 27 refs., 8 figs., 3 tabs.
- OSTI ID:
- 449165
- Journal Information:
- Journal of Catalysis, Journal Name: Journal of Catalysis Journal Issue: 1 Vol. 160; ISSN 0021-9517; ISSN JCTLA5
- Country of Publication:
- United States
- Language:
- English
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