Oxygen isotopes and trace elements in the Tiva Canyon Tuff, Yucca Mountain and vicinity, Nye County, Nevada

Technical Report · Tue Dec 31 04:00:00 EST 1996

DOI:https://doi.org/10.2172/441684· OSTI ID:441684

Marshall, B D; Kyser, T K; Peterman, Z E

Yucca Mountain is being studied as a potential site for an underground repository for high-level radioactive waste. Because Yucca Mountain is located in a resource-rich geologic setting, one aspect of the site characterization studies is an evaluation of the resource potential at Yucca Mountain. The Tiva Canyon Tuff (TCT) is a widespread felsic ash-flow sheet that is well exposed in the Yucca Mountain area. Samples of the upper part of the TCT were selected to evaluate the potential for economic mineral deposits within the Miocene volcanic section. These samples of the upper cliff and caprock subunits have been analyzed for oxygen isotopes and a large suite of elements. Oxygen isotope compositions ({delta}{sup 18}O) of the TCT are typical of felsic igneous rocks but range from 6.9 to 11.8 permil, indicating some post-depositional alteration. There is no evidence of the low {delta}{sup 18}O values (less than 6 permil) that are typical of epithermal precious-metal deposits in the region. The variation in oxygen isotope ratios is probably the result of deuteric alteration during late-stage crystallization of silica and low-temperature hydration of glassy horizons; these processes are also recorded by the chemical compositions of the rocks. However, most elemental contents in the TCT reflect igneous processes, and the effects of alteration are observed only in some of the more mobile elements. These studies indicate that the TCT at Yucca Mountain has not been affected by large-scale meteoric-water hydrothermal circulation. The chemical compositions of the TCT, especially the low concentrations of most trace elements including typical pathfinder elements, show no evidence for epithermal metal deposits. Together, these data indicate that the potential for economic mineralization in this part of the volcanic section at Yucca Mountain is small.

• Research Organization: Geological Survey, Denver, CO (United States)
• Sponsoring Organization: USDOE Office of Civilian Radioactive Waste Management, Washington, DC (United States)
• DOE Contract Number: AI08-92NV10874
• OSTI ID: 441684
• Report Number(s): USGS-OFR--95-431; ON: DE97003356
• Country of Publication: United States
• Language: English

Related Subjects

05 NUCLEAR FUELS
29 ENERGY PLANNING, POLICY, AND ECONOMY
BARIUM
CALCIUM
CERIUM
EXPERIMENTAL DATA
GEOCHEMISTRY
LAND USE
LANTHANUM
MINERAL RESOURCES
NIOBIUM
OXYGEN ISOTOPES
POTASSIUM
RADIOACTIVE WASTE DISPOSAL
RESOURCE POTENTIAL
RUBIDIUM
SITE CHARACTERIZATION
STRONTIUM
TITANIUM
YUCCA MOUNTAIN
ZIRCONIUM