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Wetting and spreading of individual latex particles

Conference ·
OSTI ID:441516
; ;  [1]; ; ;  [2]
  1. Univ. of Maine, Orono, ME (United States)
  2. Mansoura Univ. (Egypt)

The wetting and spreading of individual latex particles is an important factor in controlling the mechanical properties of coatings such as those used on paper. The interactions between latex particles that lead to coalescence and film formation has been extensively studied and the basic mechanisms have been identified. Surface aspects of the coalescence and film formation for bulk films and dense monolayers have also been studied including the effects of surfactants. However, in many practical applications, including most paper coatings, latex is present in concentrations that are too small for latex-latex interactions to be important. In these applications, the wetting, spreading, and adhesion of individual latex particles on surfaces of the other constituents of the coating are most important. In spite of its importance, this topic has received little attention. This paper describes measurements of the contact angle {theta} and determination of the work of adhesion W of styrene-butadiene latex particles on calcite, mica, cellophane, and polystyrene surfaces. The effects of humidity and latex glass transition temperature on the wetting and spreading are also described. Some implications for the strength of coatings containing low levels of latex binders are also discussed.

OSTI ID:
441516
Report Number(s):
CONF-960214--
Country of Publication:
United States
Language:
English

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