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Kevlar fiber-epoxy adhesion and its effect on composite mechanical and fracture properties by plasma and chemical treatment

Conference ·
OSTI ID:441498
; ;  [1]
  1. National Central Univ., Chung-Li (Taiwan, Province of China)

Kevlar 49 fibers were surface modified by gas (ammonia, oxygen, and water vapor) plasmas etching and chlorosulfonation and subsequent reaction with some reagents (glycine, deionized water, ethylenediamine, and 1-butanol) to improve the adhesion to epoxy resin. After these treatments, the changes in fiber topography, chemical compositions of the fiber surfaces and the surface functional groups introduced to the surface of fibers were identified by SEM XPS and static SIMS. Interlaminar shear strength (ILSS) and T-peel strength between the fiber and epoxy resin were markedly improved by gas plasma and chlorosulfonation (0.1% and 0.25% ClSO{sub 3}H at 30 s). However, it is clear from the similar G{sub IC} values of the treated and untreated fiber composites that the fiber/matrix interfacial bond strength is only a minor contributor to G{sub IC}. SEM was also used to study the surface topography of the fracture surfaces of composites in T-peel test.

OSTI ID:
441498
Report Number(s):
CONF-960214--
Country of Publication:
United States
Language:
English

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