Iridium(III) salts as homogeneous metal catalysts for hydrogen isotope exchange in organic compounds: a comparison with heterogeneous iridium for the deuteriation of alkylbenzenes

Journal Article · Wed Oct 10 00:00:00 EDT 1973 · J. Chem. Soc., Chem. Commun., no. 19, pp. 749-750

DOI:https://doi.org/10.1039/c39730000749· OSTI ID:4408519

Garnett, J L; Long, M A; McLaren, A B; Peterson, K B

Hydrogen exchange between organic compounds and heawy water is homogeneously catalysed by sodium chloroiridite; resuits for alkylbenzenes are compared with those from heterogeneous catalysis by iridium metal and are interpreted in terms of the role of pi -complex intermediates. (auth)

• Research Organization: Univ. of New South Wales, Kensington, Australia
• NSA Number: NSA-29-002515
• OSTI ID: 4408519
• Journal Information: J. Chem. Soc., Chem. Commun., no. 19, pp. 749-750, Journal Name: J. Chem. Soc., Chem. Commun., no. 19, pp. 749-750; ISSN JCCCA
• Country of Publication: United Kingdom
• Language: English

Related Subjects

*DEUTERIUM-- ISOTOPIC EXCHANGE
AROMATICS
CATALYSIS
CATALYSTS
COMPARATIVE EVALUATIONS
DEUTERATION
HEAVY WATER
HYDROGEN
IRIDIUM
IRIDIUM CHLORIDES
IRIDIUM COMPLEXES
N40300* --Chemistry--Radiation Chemistry
SODIUM CHLORIDES