Antagonistic effects in reverse phase partition and solvent extraction of Ru(III) from HCl solutions
Journal Article
·
· Indian J. Chem., v. 11, no. 5, pp. 490-493
OSTI ID:4399529
The antagonistic effects of n-octanol, cyclohexanol, and chloroform on the reverse phase partition and extraction of Ru(III) by tri-n-octylphosphine (TOP), tri-n-octylphosphine oxide (TOPO), tri-n-butylphosphine oxide (TBPO), tri- n-hexylamine (THA), and tricaprylmethy1ammonium chloride (Aliquat-336) were studied. It is found that the decrease in partition of Ru(IIII) in the presence of n-octanol and cyclohexanol is due to the adduct formation of these antagonistic with TOP, TOPO, TBPO, THA, and Aliquat-336, thereby reducing the free STAextractant!. Similar behavior was noticed during liquid--liquid extraction also. (auth)
- Research Organization:
- Bhabha Atomic Research Centre, Trombay, India
- NSA Number:
- NSA-29-000116
- OSTI ID:
- 4399529
- Journal Information:
- Indian J. Chem., v. 11, no. 5, pp. 490-493, Journal Name: Indian J. Chem., v. 11, no. 5, pp. 490-493; ISSN IJOCA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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