Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

High-resolution solid-state {sup 13}C and {sup 15}N NMR spectroscopy of pyrazole and 3,5-dimethylpyrazole adsorbed on alumina and silica

Journal Article · · Journal of Physical Chemistry
;  [1];  [2]
  1. Ciudad Universitaria, Madrid (Spain)
  2. Instituto de Quimica Medica, Madrid (Spain); and others
Using pyrazole and 3,5-dimethylpyrazole mixtures with alumina and silica, high-resolution solid state {sup 13}C and {sup 15}N CPMAS NMR was performed to compare the spectra. The NH-N proton tautomers resulting depend strongly on the environment. 70 refs., 8 figs., 4 tabs.
Sponsoring Organization:
USDOE
OSTI ID:
437454
Journal Information:
Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 35 Vol. 98; ISSN JPCHAX; ISSN 0022-3654
Country of Publication:
United States
Language:
English

Similar Records

Dehydration of silica-aluminas monitored by high-resolution solid-state proton NMR
Journal Article · Tue Mar 03 23:00:00 EST 1987 · J. Am. Chem. Soc.; (United States) · OSTI ID:6802139

Intermolecular triple proton and deuteron transfer in crystalline 3,5-dimethylpyrazole studied by NMR, NQR, and x-ray methods
Journal Article · Wed Sep 13 00:00:00 EDT 1989 · Journal of the American Chemical Society; (USA) · OSTI ID:6724815

Fate of (/sup 15/N)glycine in peat as determined by /sup 13/C and /sup 15/N CP-MAS NMR spectroscopy
Journal Article · · J. Agric. Food Chem.; (United States) · OSTI ID:5931458